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Episode | Date |
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24.0 Amines and heterocycles
|
Apr 18, 2011 |
24.1 Nomenclature of amines
|
Apr 18, 2011 |
24.2 Properties of amines
|
Apr 18, 2011 |
24.3 Basicity of amines
|
Apr 18, 2011 |
24.4 Basicity of substituted arylamines
|
Apr 18, 2011 |
24.5 Biological amines and the H-H equation
|
Apr 18, 2011 |
24.6 Synthesis of amines
|
Apr 18, 2011 |
24.7 Hoffman elimination
|
Apr 18, 2011 |
24.8 Reactions of arylamines
|
Apr 18, 2011 |
24.9 Heterocycles
|
Apr 18, 2011 |
24.10 Spectroscopy of amines
|
Apr 18, 2011 |
23.0 Carbonyl condensation reactions
|
Apr 12, 2011 |
23.1 Aldol reaction
|
Apr 12, 2011 |
23.2 Carbonyl condensations vs. alpha alkylation
|
Apr 12, 2011 |
23.3 Dehydration of aldol products - enones
|
Apr 12, 2011 |
23.4 Using aldol reactions in synthesis
|
Apr 12, 2011 |
23.5 Mixed aldol reactions
|
Apr 12, 2011 |
23.6 Intramolecular aldol reaction
|
Apr 12, 2011 |
23.7 The Claisen condensation reaction
|
Apr 12, 2011 |
23.8 Mixed Claisen reactions
|
Apr 12, 2011 |
23.9 Intramolecular Claisen condensations - Dieckmann
|
Apr 12, 2011 |
23.10 Conjugate carbonyl additions - Michael reaction
|
Apr 12, 2011 |
23.11 Carbonyl condensations with enamines - Stork reaction
|
Apr 12, 2011 |
23.12 Robinson annulation
|
Apr 12, 2011 |
Summary of carbonyl condensation reactions
|
Apr 12, 2011 |
22.0 Carbonyl alpha-substitution reactions
|
Apr 10, 2011 |
22.1 Keto-enol tautomerism
|
Apr 10, 2011 |
22.2 Reactivity of enols
|
Apr 10, 2011 |
22.3 Alpha halogenation of aldehydes and ketones
|
Apr 10, 2011 |
22.4 Alpha bromination of carboxylic acids - HVZ reaction
|
Apr 10, 2011 |
22.5 Acidity of alpha hydrogens - enolate formation
|
Apr 10, 2011 |
22.6 Reactivity of enolate ions
|
Apr 10, 2011 |
22.7a Alkylation of enolate ions
|
Apr 10, 2011 |
22.7b Malonic and acetoacetic ester syntheses
|
Apr 10, 2011 |
22.7c Direct alkylation of ketones, esters, nitriles
|
Apr 10, 2011 |
21.0 Carboxylic acid derivatives
|
Apr 09, 2011 |
21.1 Naming carbox acid derivatives
|
Apr 09, 2011 |
21.2 Nucleophilic acyl substitution
|
Apr 09, 2011 |
21.3 Reactions of carboxylic acids
|
Apr 09, 2011 |
21.4 Chemistry of acid halides
|
Apr 09, 2011 |
21.5 Chemistry of acid anhydrides
|
Apr 09, 2011 |
21.6 Chemistry of esters
|
Apr 09, 2011 |
21.7 Chemistry of amides
|
Apr 09, 2011 |
21.8 Biological thioesters and acyl phosphates
|
Apr 09, 2011 |
21.9 Polyamides and polyesters
|
Apr 09, 2011 |
21.10 Spectroscopy of CADs
|
Apr 09, 2011 |
20.1 Nomenclature of carboxylic acids
|
Mar 07, 2011 |
20.2 Structure and properties of carboxylic acids
|
Mar 07, 2011 |
20.3 Biological acids and the H-H equation
|
Mar 07, 2011 |
20.4 Substituent effects on acidity
|
Mar 07, 2011 |
20.5 Preparation of carboxylic acids
|
Mar 07, 2011 |
20.8 Spectroscopy of carboxylic acids
|
Mar 07, 2011 |
19.1 Aldehydes and ketones
|
Feb 27, 2011 |
19.2 Preparation of aldehydes and ketones
|
Feb 27, 2011 |
19.3 Oxidation of aldehydes and ketones
|
Feb 27, 2011 |
19.4 Nucleophilic addition reactions of aldehydes and ketones
|
Feb 27, 2011 |
19.5 Hydration of aldehydes and ketones
|
Feb 27, 2011 |
19.6 Addition of HCN - cyanohydrin formation
|
Feb 27, 2011 |
19.7 Addition of Grignard and hydride reagents - alcohol formation
|
Feb 27, 2011 |
19.8 Addition of amines - imine and enamine formation
|
Feb 27, 2011 |
19.10 Addition of alcohols - acetal formation
|
Feb 27, 2011 |
19.11 The Wittig reaction
|
Feb 27, 2011 |
19.13 Conjugate addition to unsaturated aldehydes and ketones
|
Feb 27, 2011 |
19.14a Spectroscopy of aldehydes and ketones
|
Feb 27, 2011 |
19.14b Spectroscopy answers
|
Feb 27, 2011 |
18.1 Nomenclature of ethers
|
Feb 17, 2011 |
18.2 Synthesis of ethers
|
Feb 17, 2011 |
18.3 Acidic cleavage of ethers
|
Feb 17, 2011 |
18.5 Cyclic ethers, epoxides
|
Feb 17, 2011 |
18.6 Ring-opening of epoxides
|
Feb 17, 2011 |
18.8 Thiols and sulfides
|
Feb 17, 2011 |
18.9 Spectroscopy of ethers
|
Feb 17, 2011 |
17.1 Nomenclature of alcohols and phenols
|
Feb 11, 2011 |
17.2 Properties of alcohols and phenols
|
Feb 11, 2011 |
17.3 Preparation of alcohols
|
Feb 11, 2011 |
17.4 Alcohols from reduction of carbonyl compounds
|
Feb 11, 2011 |
17.5 Alcohols from the Grignard reaction
|
Feb 11, 2011 |
17.6a Reactions of alcohols
|
Feb 11, 2011 |
17.6b Tosylates
|
Feb 11, 2011 |
17.6c Dehydration and esterification
|
Feb 11, 2011 |
17.7 Oxidation of alcohols
|
Feb 11, 2011 |
17.8 Protection of alcohols
|
Feb 11, 2011 |
17.11 Spectroscopy of alcohols
|
Feb 11, 2011 |
16.1 EAS - bromination
|
Jan 28, 2011 |
16.2 Other aromatic substitutions
|
Jan 28, 2011 |
16.3 The Friedel-Crafts reaction
|
Jan 28, 2011 |
16.4 Substituent effects in aromatic rings
|
Jan 28, 2011 |
16.5 An explanation of substituent effects
|
Jan 28, 2011 |
16.6 Trisubstituted benzenes - additivity of effects
|
Jan 28, 2011 |
16.9 Oxidation of aromatic compounds
|
Jan 28, 2011 |
16.10 Reduction of aromatic compounds
|
Jan 28, 2011 |
16.11a Synthesis of trisubstituted benzenes
|
Jan 28, 2011 |
16.11b Synthesis answers
|
Jan 28, 2011 |
16.11c A challenging example
|
Jan 28, 2011 |
15.0 Benzene and aromaticity
|
Jan 21, 2011 |
15.1 Sources and names of aromatic compounds
|
Jan 21, 2011 |
15.2 Molecular orbitals of benzene
|
Jan 21, 2011 |
15.3 Aromaticity and the Huckel rule
|
Jan 21, 2011 |
15.4 Aromatic ions
|
Jan 21, 2011 |
15.5 Aromatic heterocycles
|
Jan 21, 2011 |
15.7 Polycyclic aromatic compounds
|
Jan 21, 2011 |
15.8 Spectroscopy of aromatic compounds
|
Jan 21, 2011 |
14.1 Conjugated compounds
|
Jan 15, 2011 |
14.2 Allylic carbocations
|
Jan 15, 2011 |
14.3 Kinetic vs thermodynamic control of reactions
|
Jan 15, 2011 |
14.4 The Diels-Alder cycloaddition reaction
|
Jan 15, 2011 |
Problem-solving with the Diels-Alder reaction
|
Jan 15, 2011 |
14.7 UV spectroscopy
|
Jan 15, 2011 |
12.1 Mass spectrometry
|
Jan 15, 2011 |
12.2 Interpreting mass spectra
|
Jan 15, 2011 |
12.3 MS of some common functional groups
|
Jan 15, 2011 |
12.5 Spectroscopy and the EM spectrum
|
Jan 15, 2011 |
12.6 IR spectroscopy
|
Jan 15, 2011 |
12.7 Interpreting IR spectra
|
Jan 15, 2011 |
12.8 IR spectra of some common functional groups
|
Jan 15, 2011 |
11.1 Substitutions and eliminations
|
Nov 19, 2010 |
11.2 The Sn2 reaction
|
Nov 19, 2010 |
11.3 Characteristics of the Sn2 reaction
|
Nov 19, 2010 |
11.4 The Sn1 reaction
|
Nov 19, 2010 |
11.5 Characteristics of the Sn1 reaction
|
Nov 19, 2010 |
11.7 Elimination reactions of alkyl halides - Zaitsev's rule
|
Nov 19, 2010 |
11.8 The E2 reaction
|
Nov 19, 2010 |
11.9 The E2 reaction and cyclohexane conformation
|
Nov 19, 2010 |
11.10 The E1 reaction
|
Nov 19, 2010 |
11.12 Summary of reactivity
|
Nov 19, 2010 |
11 Synthesis practice
|
Nov 19, 2010 |
11 Sythesis practice key
|
Nov 19, 2010 |
10.0 Alkyl halides
|
Nov 12, 2010 |
10.2 Structure of alkyl halides
|
Nov 12, 2010 |
10.3 Radical halogenation
|
Nov 12, 2010 |
10.4 Allylic bromination
|
Nov 12, 2010 |
10.5 Stability of the allylic radical
|
Nov 12, 2010 |
10.6 Preparing alkyl halides from alcohols
|
Nov 12, 2010 |
10.7 Grignard reagents
|
Nov 12, 2010 |
10.8 Organometallic coupling reagents
|
Nov 12, 2010 |
10.9 Oxidation and reduction
|
Nov 12, 2010 |
9.0 Stereochemistry
|
Nov 06, 2010 |
9.1 Enantiomers and tetrahedral carbon
|
Nov 06, 2010 |
9.2 Chirality
|
Nov 06, 2010 |
9.3 Optical activity
|
Nov 06, 2010 |
9.4 Pasteur and enantiomers
|
Nov 06, 2010 |
9.5 R and S
|
Nov 06, 2010 |
9.6 Diastereomers
|
Nov 06, 2010 |
9.7 Meso compounds
|
Nov 06, 2010 |
9.8 Racemic mixtures
|
Nov 06, 2010 |
9.9 Review of isomerism
|
Nov 06, 2010 |
9.10 Addition of H2O to an achiral alkene
|
Nov 06, 2010 |
9.11 Addition of H2O to a chiral alkene
|
Nov 06, 2010 |
8.1 Alkyne nomenclature
|
Oct 22, 2010 |
8.2 Prep of alkynes
|
Oct 22, 2010 |
8.3 Addition of HX
|
Oct 22, 2010 |
8.4 Hydration and tautomerism
|
Oct 22, 2010 |
8.5 Reduction of alkynes
|
Oct 22, 2010 |
8.6 Oxidative cleavage
|
Oct 22, 2010 |
8.7 Alkyne aciditity - formation of acetylide ions
|
Oct 22, 2010 |
8.8 Alkylation of acetylide ions
|
Oct 22, 2010 |
8.9 An introduction to multistep organic synthesis
|
Oct 22, 2010 |
8 Synthesis practice
|
Oct 22, 2010 |
7.0 Alkenes - reactions and synthesis
|
Oct 14, 2010 |
7.1 Prep of alkenes - preview
|
Oct 14, 2010 |
7.2 Addition of halogens to alkenes
|
Oct 14, 2010 |
7.3 Halohydrin formation
|
Oct 14, 2010 |
7.4 Hydration of alkenes - oxymercuration
|
Oct 14, 2010 |
7.5 Hydration of alkenes - hydroboration
|
Oct 14, 2010 |
7.6 Addition of carbenes to alkenes
|
Oct 14, 2010 |
7.7 Reduction of alkenes - hydrogenation
|
Oct 14, 2010 |
7.8 Oxidation of alkenes - epoxidation and dihydroxylation
|
Oct 14, 2010 |
7.9 Oxidation of alkenes - cleavage to carbonyl compounds
|
Oct 14, 2010 |
7.10 Polymers
|
Oct 14, 2010 |
6.1 Alkenes - structure and reactivity
|
Oct 07, 2010 |
6.2 Degree of unsaturation
|
Oct 07, 2010 |
6.3 Naming alkenes
|
Oct 07, 2010 |
6.4 Cis-trans isomerism in alkenes
|
Oct 07, 2010 |
6.5 The E-Z designation
|
Oct 07, 2010 |
6.6 Stability of alkenes
|
Oct 07, 2010 |
6.7 Electrophilic addition reactions of alkenes
|
Oct 07, 2010 |
6.8 Markovnikov's rule
|
Oct 07, 2010 |
6.9 Carbocation structure and stability
|
Oct 07, 2010 |
6.10 The Hammond postulate
|
Oct 07, 2010 |
6.11 Carbocation rearrangements
|
Oct 07, 2010 |
5.1 An overview of organic reactions
|
Oct 01, 2010 |
5.2 Mechanisms
|
Oct 01, 2010 |
5.3 Radical reactions
|
Oct 01, 2010 |
5.4 Polar reactions
|
Oct 01, 2010 |
5.5 Addition of HBr to ethylene
|
Oct 01, 2010 |
5.6 Using curved arrows in polar reaction mechanisms
|
Oct 01, 2010 |
5.7 Equilibria, rates, and energy changes
|
Oct 01, 2010 |
5.8 Bond dissociation energies
|
Oct 01, 2010 |
5.9 Energy diagrams and transition states
|
Oct 01, 2010 |
5.10 Intermediates
|
Oct 01, 2010 |
4.0 - Cycloalkanes and their stereochemistry
|
Sep 16, 2010 |
4.1 - Naming cycloalkanes
|
Sep 16, 2010 |
4.2 - Cis-trans isomerism in cycloalkanes
|
Sep 16, 2010 |
4.3 - Ring strain
|
Sep 16, 2010 |
4.4 - Conformations of cycloalkanes
|
Sep 16, 2010 |
4.5 - Conformations of cyclohexane
|
Sep 16, 2010 |
4.6 - Axial and equatorial bonds in cyclohexane
|
Sep 16, 2010 |
4.7 - Conformations of monosubstituted cyclohexanes
|
Sep 16, 2010 |
4.8 - Conformations of disubstituted cyclohexanes
|
Sep 16, 2010 |
4.9 - Conformations of polycyclic molecules
|
Sep 16, 2010 |
3.1 - Intro to alkanes and their stereochemistry
|
Sep 07, 2010 |
3.2 - Alkanes and alkane isomers
|
Sep 07, 2010 |
3.3 - Alkyl groups
|
Sep 07, 2010 |
3.4 - Naming alkanes
|
Sep 07, 2010 |
3.5 - Properties of alkanes
|
Sep 07, 2010 |
3.6 - Conformations of ethane
|
Sep 07, 2010 |
3.7 - Conformations of other alkanes
|
Sep 07, 2010 |
2.0 - Intro
|
Aug 26, 2010 |
2.2 - Dipole moments
|
Aug 26, 2010 |
2.3 - Formal charges
|
Aug 26, 2010 |
2.4 - Resonance
|
Aug 26, 2010 |
2.7 - Acids and bases - the Bronsted Lowry definition
|
Aug 26, 2010 |
2.8 - Acid and base strength
|
Aug 26, 2010 |
2.9 - Predicting the direction of acid-base reactions
|
Aug 26, 2010 |
2.10 - Organic acids
|
Aug 26, 2010 |
2.11 - Acids and bases - the Lewis definition
|
Aug 26, 2010 |
2.13 - Non-covalent interactions
|
Aug 26, 2010 |
Orientation
|
Aug 24, 2010 |
1.0 - Intro to structure and bonding
|
Aug 17, 2010 |
1.1 - The nucleus
|
Aug 17, 2010 |
1.2 - Orbitals
|
Aug 17, 2010 |
1.3 - Electron configurations
|
Aug 17, 2010 |
1.5 - Valence bond theory
|
Aug 17, 2010 |
1.4 - Development of chemical bonding theory
|
Aug 17, 2010 |
1.6 - Structure of methane
|
Aug 17, 2010 |
1.7 - Structure of ethane
|
Aug 17, 2010 |
1.8 - sp2 hybrid orbitals and the structure of ethylene
|
Aug 17, 2010 |
1.9 - sp hybrid orbitals and the structure of acetylene
|
Aug 17, 2010 |
1.10 - Hybridization of N and O
|
Aug 17, 2010 |
1.11 - Molecular orbital theory
|
Aug 17, 2010 |
1.12 - Drawing structures
|
Aug 17, 2010 |